##TITLE=NP0000292, Submission ID 687, Experimental spectrum ##JCAMP-DX=4.24 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=LINK ##DATE=23/04/28 ##TIME=22:34:09 ##LONG DATE=2023/04/28 22:34:09 ##TITLE=N-Methylhydantoin ##JCAMP-CS=3.7 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATE=23/04/28 ##TIME=22:34:09 ##BLOCK_ID=1 ##CROSS REFERENCE=NMR PEAK ASSIGNMENTS:BLOCK_ID=4 ##LONG DATE=2023/04/28 22:34:09 ##MOLFORM=C4 H6 N2 O2 ##ATOMLIST= 1 C 0 2 N 0 3 C 0 4 C 0 5 O 0 6 N 0 7 C 0 8 O 0 9 H 0 10 H 0 11 H 0 12 H 0 13 H 0 14 H 0 ##BONDLIST= 1 2 S 2 3 S 3 4 S 4 5 D 4 6 S 6 7 S 7 8 D 7 2 S 1 9 S 1 10 S 1 11 S 3 12 S 3 13 S 6 14 S ##$MOLFILE= RDKit 3D 14 14 0 0 0 0 0 0 0 0999 V2000 1.9525 0.0266 0.0010 C 0 0 2 0 0 0 0 0 0 0 0 0 0.5050 0.1074 -0.1110 N 0 0 0 0 0 0 0 0 0 0 0 0 -0.3615 -1.0455 -0.2526 C 0 0 2 0 0 0 0 0 0 0 0 0 -1.6207 -0.5522 0.3570 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.4713 -1.2788 0.9132 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.6592 0.8579 0.1854 N 0 0 0 0 0 0 0 0 0 0 0 0 -0.3214 1.2527 -0.1069 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0753 2.4309 -0.3283 O 0 0 0 0 0 0 0 0 0 0 0 0 2.3483 0.8834 0.5899 H 0 0 0 0 0 0 0 0 0 0 0 0 2.3872 -0.0875 -0.9866 H 0 0 0 0 0 0 0 0 0 0 0 0 2.1767 -0.8977 0.5811 H 0 0 0 0 0 0 0 0 0 0 0 0 0.0524 -1.9302 0.2435 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.5482 -1.2226 -1.3504 H 0 0 0 0 0 0 0 0 0 0 0 0 -2.5152 1.4559 0.2648 H 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 2 3 1 0 3 4 1 0 4 5 2 0 4 6 1 0 6 7 1 0 7 8 2 0 7 2 1 0 1 9 1 1 1 10 1 0 1 11 1 0 3 12 1 1 3 13 1 0 6 14 1 0 M END ##END= ##TITLE=Experimental spectrum ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR SPECTRUM ##BLOCK_ID=2 ##DATE=23/04/28 ##TIME=22:34:09 ##TEMPERATURE=NA ##LONG DATE=2023/04/28 22:34:09 ##.OBSERVE FREQUENCY=700.0 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##.SHIFT REFERENCE=INTERNAL,DSS,235742.98,0 ##XUNITS=PPM ##FIRSTX=10.808958306324364 ##LASTX=-1.210456740096376 ##MINX=-1.210456740096376 ##MAXX=10.808958306324364 ##XFACTOR=4.585060461792523e-05 ##NPOINTS=262144 ##YUNITS=ARBITRARY UNITS ##FIRSTY=0.05906599063376948 ##LASTY=0.03188081291869772 ##MINY=-2554.89225104175 ##MAXY=10000.0 ##YFACTOR=0.3051850947599719 ##XYDATA=(X++(Y..Y)), XYDATA $$ DIF 235743@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 235670@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 235597@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 235524@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 235451@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 235378@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 235305@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 235232@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 235159@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 235086@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 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-25886@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25959@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%j%J%%%%%%%jJ%%%%%%%%%%% -26032@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -26105@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%jJ%%%%%%%%%%%%%%%%%%%%%% -26178@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -26251@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -26324@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -26397@%%% -26400@ $$ checkpoint ##END= ##TITLE=Peaks ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK TABLE ##DATA CLASS=PEAK TABLE ##BLOCK_ID=3 ##DATE=23/04/28 ##TIME=22:34:09 ##TEMPERATURE=NA ##LONG DATE=2023/04/28 22:34:09 ##.OBSERVE FREQUENCY=700.0 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##NPOINTS=827 ##XUNITS=PPM ##YUNITS=ARBITRARY UNITS ##PEAK TABLE=(XY..XY) (9.0564564966087, 0.3404500467520837) 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(2.946359074586848, 0.9438279054302484) (2.945992269749903, 0.9318874442492046) (2.9431495322635755, 0.9297856009242902) (2.9438372913328488, 0.9272781534073931) (2.9427827274266303, 0.9194502734317462) (2.9434704864959027, 0.8950243550899561) (2.946725879423793, 0.8526334675425108) (2.9456254649129567, 0.846073613263857) (2.9474136384930656, 0.8415837040989808) (2.9470468336561204, 0.8117284003531284) ##END= ##TITLE=Assignments ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK ASSIGNMENTS ##DATA CLASS=PEAK ASSIGNMENTS ##BLOCK_ID=4 ##CROSS REFERENCE=STRUCTURE:BLOCK_ID=1 ##DATE=23/04/28 ##TIME=22:34:09 ##TEMPERATURE=NA ##LONG DATE=2023/04/28 22:34:09 ##SOURCE REFERENCE=PMID 7482520 ##.OBSERVE FREQUENCY=700.0 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##NPOINTS=5 ##XUNITS=PPM ##PEAK ASSIGNMENTS=(XMA) (2.92, , <9>) (2.92, , <10>) (2.92, , <11>) (4.08, , <12>) (4.08, , <13>) ##END= ##END= ##TITLE=NP0000292, Submission ID 687, Experimental spectrum ##JCAMP-DX=4.24 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=LINK ##DATE=23/04/28 ##TIME=22:34:28 ##LONG DATE=2023/04/28 22:34:28 ##TITLE=N-Methylhydantoin ##JCAMP-CS=3.7 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATE=23/04/28 ##TIME=22:34:28 ##BLOCK_ID=1 ##CROSS REFERENCE=NMR PEAK ASSIGNMENTS:BLOCK_ID=4 ##LONG DATE=2023/04/28 22:34:28 ##MOLFORM=C4 H6 N2 O2 ##ATOMLIST= 1 C 0 2 N 0 3 C 0 4 C 0 5 O 0 6 N 0 7 C 0 8 O 0 9 H 0 10 H 0 11 H 0 12 H 0 13 H 0 14 H 0 ##BONDLIST= 1 2 S 2 3 S 3 4 S 4 5 D 4 6 S 6 7 S 7 8 D 7 2 S 1 9 S 1 10 S 1 11 S 3 12 S 3 13 S 6 14 S ##$MOLFILE= RDKit 3D 14 14 0 0 0 0 0 0 0 0999 V2000 1.9525 0.0266 0.0010 C 0 0 2 0 0 0 0 0 0 0 0 0 0.5050 0.1074 -0.1110 N 0 0 0 0 0 0 0 0 0 0 0 0 -0.3615 -1.0455 -0.2526 C 0 0 2 0 0 0 0 0 0 0 0 0 -1.6207 -0.5522 0.3570 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.4713 -1.2788 0.9132 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.6592 0.8579 0.1854 N 0 0 0 0 0 0 0 0 0 0 0 0 -0.3214 1.2527 -0.1069 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0753 2.4309 -0.3283 O 0 0 0 0 0 0 0 0 0 0 0 0 2.3483 0.8834 0.5899 H 0 0 0 0 0 0 0 0 0 0 0 0 2.3872 -0.0875 -0.9866 H 0 0 0 0 0 0 0 0 0 0 0 0 2.1767 -0.8977 0.5811 H 0 0 0 0 0 0 0 0 0 0 0 0 0.0524 -1.9302 0.2435 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.5482 -1.2226 -1.3504 H 0 0 0 0 0 0 0 0 0 0 0 0 -2.5152 1.4559 0.2648 H 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 2 3 1 0 3 4 1 0 4 5 2 0 4 6 1 0 6 7 1 0 7 8 2 0 7 2 1 0 1 9 1 1 1 10 1 0 1 11 1 0 3 12 1 1 3 13 1 0 6 14 1 0 M END ##END= ##TITLE=Experimental spectrum ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR SPECTRUM ##BLOCK_ID=2 ##DATE=23/04/28 ##TIME=22:34:28 ##TEMPERATURE=NA ##LONG DATE=2023/04/28 22:34:28 ##.OBSERVE FREQUENCY=700.0 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##.SHIFT REFERENCE=INTERNAL,DSS,235742.98,0 ##XUNITS=PPM ##FIRSTX=10.808958306324364 ##LASTX=-1.210456740096376 ##MINX=-1.210456740096376 ##MAXX=10.808958306324364 ##XFACTOR=4.585060461792523e-05 ##NPOINTS=262144 ##YUNITS=ARBITRARY UNITS ##FIRSTY=0.05906599063376948 ##LASTY=0.03188081291869772 ##MINY=-2554.89225104175 ##MAXY=10000.0 ##YFACTOR=0.3051850947599719 ##XYDATA=(X++(Y..Y)), XYDATA $$ DIF 235743@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 235670@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 235597@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 235524@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 235451@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 235378@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 235305@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 235232@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 235159@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 235086@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 235013@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 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-24207@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -24280@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -24353@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -24426@%%%%%%%%%%%%%%J%j%%%%%%%%%%%%%%%%%%J%%%j%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -24499@%%%%%%%Jj%%%%%%%%%%%%%%%Jj%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -24572@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%Jj%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -24645@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -24718@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -24791@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -24864@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -24937@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25010@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25083@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25156@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25229@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25302@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25375@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25448@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25521@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25594@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25667@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25740@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25813@%%%%%%%%J%j%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25886@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25959@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%j%J%%%%%%%jJ%%%%%%%%%%% -26032@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -26105@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%jJ%%%%%%%%%%%%%%%%%%%%%% -26178@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -26251@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -26324@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -26397@%%% -26400@ $$ checkpoint ##END= ##TITLE=Peaks ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK TABLE ##DATA CLASS=PEAK TABLE ##BLOCK_ID=3 ##DATE=23/04/28 ##TIME=22:34:28 ##TEMPERATURE=NA ##LONG DATE=2023/04/28 22:34:28 ##.OBSERVE FREQUENCY=700.0 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##NPOINTS=827 ##XUNITS=PPM ##YUNITS=ARBITRARY UNITS ##PEAK TABLE=(XY..XY) (9.0564564966087, 0.3404500467520837) (9.052146539774592, 0.33881014680902793) (9.050495918008338, 0.38274725114948177) 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(2.9431495322635755, 0.9297856009242902) (2.9438372913328488, 0.9272781534073931) (2.9427827274266303, 0.9194502734317462) (2.9434704864959027, 0.8950243550899561) (2.946725879423793, 0.8526334675425108) (2.9456254649129567, 0.846073613263857) (2.9474136384930656, 0.8415837040989808) (2.9470468336561204, 0.8117284003531284) ##END= ##TITLE=Assignments ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK ASSIGNMENTS ##DATA CLASS=PEAK ASSIGNMENTS ##BLOCK_ID=4 ##CROSS REFERENCE=STRUCTURE:BLOCK_ID=1 ##DATE=23/04/28 ##TIME=22:34:28 ##TEMPERATURE=NA ##LONG DATE=2023/04/28 22:34:28 ##SOURCE REFERENCE=PMID 7482520 ##.OBSERVE FREQUENCY=700.0 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##NPOINTS=5 ##XUNITS=PPM ##PEAK ASSIGNMENTS=(XMA) (2.92, , <9>) (2.92, , <10>) (2.92, , <11>) (4.08, , <12>) (4.08, , <13>) ##END= ##END= ##TITLE=NP0000292, Submission ID 687, Experimental spectrum ##JCAMP-DX=4.24 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=LINK ##DATE=23/04/28 ##TIME=22:34:51 ##LONG DATE=2023/04/28 22:34:51 ##TITLE=N-Methylhydantoin ##JCAMP-CS=3.7 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATE=23/04/28 ##TIME=22:34:51 ##BLOCK_ID=1 ##CROSS REFERENCE=NMR PEAK ASSIGNMENTS:BLOCK_ID=4 ##LONG DATE=2023/04/28 22:34:51 ##MOLFORM=C4 H6 N2 O2 ##ATOMLIST= 1 C 0 2 N 0 3 C 0 4 C 0 5 O 0 6 N 0 7 C 0 8 O 0 9 H 0 10 H 0 11 H 0 12 H 0 13 H 0 14 H 0 ##BONDLIST= 1 2 S 2 3 S 3 4 S 4 5 D 4 6 S 6 7 S 7 8 D 7 2 S 1 9 S 1 10 S 1 11 S 3 12 S 3 13 S 6 14 S ##$MOLFILE= RDKit 3D 14 14 0 0 0 0 0 0 0 0999 V2000 1.9525 0.0266 0.0010 C 0 0 2 0 0 0 0 0 0 0 0 0 0.5050 0.1074 -0.1110 N 0 0 0 0 0 0 0 0 0 0 0 0 -0.3615 -1.0455 -0.2526 C 0 0 2 0 0 0 0 0 0 0 0 0 -1.6207 -0.5522 0.3570 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.4713 -1.2788 0.9132 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.6592 0.8579 0.1854 N 0 0 0 0 0 0 0 0 0 0 0 0 -0.3214 1.2527 -0.1069 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0753 2.4309 -0.3283 O 0 0 0 0 0 0 0 0 0 0 0 0 2.3483 0.8834 0.5899 H 0 0 0 0 0 0 0 0 0 0 0 0 2.3872 -0.0875 -0.9866 H 0 0 0 0 0 0 0 0 0 0 0 0 2.1767 -0.8977 0.5811 H 0 0 0 0 0 0 0 0 0 0 0 0 0.0524 -1.9302 0.2435 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.5482 -1.2226 -1.3504 H 0 0 0 0 0 0 0 0 0 0 0 0 -2.5152 1.4559 0.2648 H 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 2 3 1 0 3 4 1 0 4 5 2 0 4 6 1 0 6 7 1 0 7 8 2 0 7 2 1 0 1 9 1 1 1 10 1 0 1 11 1 0 3 12 1 1 3 13 1 0 6 14 1 0 M END ##END= ##TITLE=Experimental spectrum ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR SPECTRUM ##BLOCK_ID=2 ##DATE=23/04/28 ##TIME=22:34:51 ##TEMPERATURE=NA ##LONG DATE=2023/04/28 22:34:51 ##.OBSERVE FREQUENCY=700.0 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##.SHIFT REFERENCE=INTERNAL,DSS,235742.98,0 ##XUNITS=PPM ##FIRSTX=10.808958306324364 ##LASTX=-1.210456740096376 ##MINX=-1.210456740096376 ##MAXX=10.808958306324364 ##XFACTOR=4.585060461792523e-05 ##NPOINTS=262144 ##YUNITS=ARBITRARY UNITS ##FIRSTY=0.05906599063376948 ##LASTY=0.03188081291869772 ##MINY=-2554.89225104175 ##MAXY=10000.0 ##YFACTOR=0.3051850947599719 ##XYDATA=(X++(Y..Y)), XYDATA $$ DIF 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-24280@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -24353@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -24426@%%%%%%%%%%%%%%J%j%%%%%%%%%%%%%%%%%%J%%%j%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -24499@%%%%%%%Jj%%%%%%%%%%%%%%%Jj%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -24572@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%Jj%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -24645@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -24718@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -24791@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -24864@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -24937@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25010@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25083@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25156@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25229@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25302@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25375@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25448@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25521@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25594@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25667@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25740@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25813@%%%%%%%%J%j%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25886@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25959@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%j%J%%%%%%%jJ%%%%%%%%%%% -26032@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -26105@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%jJ%%%%%%%%%%%%%%%%%%%%%% -26178@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -26251@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -26324@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -26397@%%% -26400@ $$ checkpoint ##END= ##TITLE=Peaks ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK TABLE ##DATA CLASS=PEAK TABLE ##BLOCK_ID=3 ##DATE=23/04/28 ##TIME=22:34:51 ##TEMPERATURE=NA ##LONG DATE=2023/04/28 22:34:51 ##.OBSERVE FREQUENCY=700.0 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##NPOINTS=827 ##XUNITS=PPM ##YUNITS=ARBITRARY UNITS ##PEAK TABLE=(XY..XY) (9.0564564966087, 0.3404500467520837) (9.052146539774592, 0.33881014680902793) (9.050495918008338, 0.38274725114948177) (9.047148823871211, 0.3393915854096385) (9.046140110569612, 0.38383256743952643) 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(2.9427827274266303, 0.9194502734317462) (2.9434704864959027, 0.8950243550899561) (2.946725879423793, 0.8526334675425108) (2.9456254649129567, 0.846073613263857) (2.9474136384930656, 0.8415837040989808) (2.9470468336561204, 0.8117284003531284) ##END= ##TITLE=Assignments ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK ASSIGNMENTS ##DATA CLASS=PEAK ASSIGNMENTS ##BLOCK_ID=4 ##CROSS REFERENCE=STRUCTURE:BLOCK_ID=1 ##DATE=23/04/28 ##TIME=22:34:51 ##TEMPERATURE=NA ##LONG DATE=2023/04/28 22:34:51 ##SOURCE REFERENCE=PMID 7482520 ##.OBSERVE FREQUENCY=700.0 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##NPOINTS=5 ##XUNITS=PPM ##PEAK ASSIGNMENTS=(XMA) (2.92, , <9>) (2.92, , <10>) (2.92, , <11>) (4.08, , <12>) (4.08, , <13>) ##END= ##END=