##TITLE=NP0000907, Submission ID 682, Experimental spectrum ##JCAMP-DX=4.24 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=LINK ##DATE=23/04/27 ##TIME=22:35:24 ##LONG DATE=2023/04/27 22:35:24 ##TITLE=3-Methylhistidine ##JCAMP-CS=3.7 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATE=23/04/27 ##TIME=22:35:24 ##BLOCK_ID=1 ##CROSS REFERENCE=NMR PEAK ASSIGNMENTS:BLOCK_ID=4 ##LONG DATE=2023/04/27 22:35:24 ##MOLFORM=C7 H11 N3 O2 ##ATOMLIST= 1 C 0 2 N 0 3 C 0 4 N 0 5 C 0 6 C 0 7 C 0 8 C 0 9 N 0 10 C 0 11 O 0 12 O 0 13 H 0 14 H 0 15 H 0 16 H 0 17 H 0 18 H 0 19 H 0 20 H 0 21 H 0 22 H 0 23 H 0 ##BONDLIST= 1 2 S 2 3 S 3 4 D 4 5 S 5 6 D 6 7 S 7 8 S 8 9 S 8 10 S 10 11 D 10 12 S 6 2 S 1 13 S 1 14 S 1 15 S 3 16 S 5 17 S 7 18 S 7 19 S 8 20 S 9 21 S 9 22 S 12 23 S ##STEREOCENTER= 8 M 0 ##$MOLFILE= RDKit 3D 23 23 0 0 0 0 0 0 0 0999 V2000 2.8554 0.1266 0.9678 C 0 0 1 0 0 0 0 0 0 0 0 0 1.9712 0.2125 -0.1987 N 0 0 0 0 0 0 0 0 0 0 0 0 2.3643 0.5251 -1.4466 C 0 0 0 0 0 0 0 0 0 0 0 0 1.2875 0.5074 -2.2510 N 0 0 0 0 0 0 0 0 0 0 0 0 0.1877 0.1839 -1.5347 C 0 0 0 0 0 0 0 0 0 0 0 0 0.6429 0.0028 -0.2449 C 0 0 0 0 0 0 0 0 0 0 0 0 -0.1658 -0.3665 0.9364 C 0 0 2 0 0 0 0 0 0 0 0 0 -1.6252 -0.5409 0.6471 C 0 0 2 0 0 0 0 0 0 0 0 0 -1.9541 -1.5285 -0.2941 N 0 0 0 0 0 0 0 0 0 0 0 0 -2.2924 0.7726 0.3783 C 0 0 0 0 0 0 0 0 0 0 0 0 -2.0867 1.7644 1.1245 O 0 0 0 0 0 0 0 0 0 0 0 0 -3.1448 0.8868 -0.7075 O 0 0 0 0 0 0 0 0 0 0 0 0 3.1812 -0.9434 1.0076 H 0 0 0 0 0 0 0 0 0 0 0 0 3.7166 0.7742 0.7921 H 0 0 0 0 0 0 0 0 0 0 0 0 2.2494 0.3843 1.8497 H 0 0 0 0 0 0 0 0 0 0 0 0 3.3988 0.7523 -1.7323 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.8183 0.0947 -1.9236 H 0 0 0 0 0 0 0 0 0 0 0 0 -0.0819 0.4721 1.6826 H 0 0 0 0 0 0 0 0 0 0 0 0 0.2176 -1.2593 1.4541 H 0 0 0 0 0 0 0 0 0 0 0 0 -2.0798 -0.8661 1.6341 H 0 0 0 0 0 0 0 0 0 0 0 0 -2.5869 -1.2778 -1.0605 H 0 0 0 0 0 0 0 0 0 0 0 0 -1.9676 -2.5051 0.0143 H 0 0 0 0 0 0 0 0 0 0 0 0 -3.2690 1.8277 -1.0951 H 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 2 3 1 0 3 4 2 0 4 5 1 0 5 6 2 0 6 7 1 0 7 8 1 0 8 9 1 0 8 10 1 0 10 11 2 0 10 12 1 0 6 2 1 0 1 13 1 1 1 14 1 0 1 15 1 0 3 16 1 0 5 17 1 0 7 18 1 1 7 19 1 0 8 20 1 1 9 21 1 0 9 22 1 0 12 23 1 0 M END ##END= ##TITLE=Experimental spectrum ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR SPECTRUM ##BLOCK_ID=2 ##DATE=23/04/27 ##TIME=22:35:24 ##TEMPERATURE=NA ##LONG DATE=2023/04/27 22:35:24 ##.OBSERVE FREQUENCY=700.0 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##.SHIFT REFERENCE=INTERNAL,DSS,235746.70,0 ##XUNITS=PPM ##FIRSTX=10.809128811916242 ##LASTX=-1.2102862345044976 ##MINX=-1.2102862345044976 ##MAXX=10.809128811916242 ##XFACTOR=4.585060461792523e-05 ##NPOINTS=262144 ##YUNITS=ARBITRARY UNITS ##FIRSTY=0.018061537715854042 ##LASTY=0.005123211226923847 ##MINY=-252.81460019404534 ##MAXY=10000.0 ##YFACTOR=0.3051850947599719 ##XYDATA=(X++(Y..Y)), XYDATA $$ DIF 235747@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 235674@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% 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-25750@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25823@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25896@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -25969@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -26042@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -26115@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -26188@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -26261@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -26334@%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% -26396@ $$ checkpoint ##END= ##TITLE=Peaks ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK TABLE ##DATA CLASS=PEAK TABLE ##BLOCK_ID=3 ##DATE=23/04/27 ##TIME=22:35:24 ##TEMPERATURE=NA ##LONG DATE=2023/04/27 22:35:24 ##.OBSERVE FREQUENCY=700.0 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##NPOINTS=654 ##XUNITS=PPM ##YUNITS=ARBITRARY UNITS ##PEAK TABLE=(XY..XY) (8.032599598658386, 0.08270837940961513) (5.693851958294809, 0.08530712597600441) (5.294034686024373, 0.09385095107431625) (5.293622030582809, 0.11794562858427779) (5.293255225745864, 0.10242804159705382) (5.292659167885828, 0.10988218356481573) (5.291558753374992, 0.1097900451046556) (5.291054396724192, 0.12236058202311292) (5.290504189468774, 0.09775777891458347) (5.290137384631828, 0.13043378309807996) (5.289449625562556, 0.10660532568972365) (5.27684070929256, 0.09279028133338237) (5.275098386317069, 0.08779924556938344) (5.146258187340013, 0.09938514149767172) (5.145111922224559, 0.08168587915814432) (5.143736404086014, 0.11622763845630325) (5.143415449853687, 0.09516928418031312) (5.142315035342851, 0.09907930754148991) (5.141948230505906, 0.085990134872496) (5.135895950696307, 0.10375628783445927) (5.135483295254744, 0.10213192406919425) (5.135116490417799, 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0.12324965241209623) (-0.03343876576994731, 0.0930130100099231) ##END= ##TITLE=Assignments ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK ASSIGNMENTS ##DATA CLASS=PEAK ASSIGNMENTS ##BLOCK_ID=4 ##CROSS REFERENCE=STRUCTURE:BLOCK_ID=1 ##DATE=23/04/27 ##TIME=22:35:24 ##TEMPERATURE=NA ##LONG DATE=2023/04/27 22:35:24 ##SOURCE REFERENCE=PMID 29968805 ##.OBSERVE FREQUENCY=700.0 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=H2O ##NPOINTS=17 ##XUNITS=PPM ##PEAK ASSIGNMENTS=(XMA) (3.75, , <13>) (3.75, , <14>) (3.75, , <15>) (8.16, , <16>) (7.17, , <17>) (3.24,
, <18>) (3.24,
, <18>) (3.24,
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, <20>) (3.96,
, <20>) ##END= ##END=