##TITLE=NP0000009, Submission ID 373, Experimental spectrum ##JCAMP-DX=4.24 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=LINK ##TITLE=Caffeine ##JCAMP-CS=3.7 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##BLOCK_ID=1 ##CROSS REFERENCE=NMR PEAK ASSIGNMENTS:BLOCK_ID=4 ##MOLFORM=C8 H10 N4 O2 ##ATOMLIST= 1 C 0 2 N 0 3 C 0 4 O 0 5 C 0 6 C 0 7 N 0 8 C 0 9 N 0 10 C 0 11 N 0 12 C 0 13 C 0 14 O 0 15 H 0 16 H 0 17 H 0 18 H 0 19 H 0 20 H 0 21 H 0 22 H 0 23 H 0 24 H 0 ##BONDLIST= 1 2 S 2 3 S 3 4 D 3 5 S 5 6 D 6 7 S 7 8 D 8 9 S 9 10 S 6 11 S 11 12 S 11 13 S 13 14 D 13 2 S 9 5 S 1 15 S 1 16 S 1 17 S 8 18 S 10 19 S 10 20 S 10 21 S 12 22 S 12 23 S 12 24 S ##$MOLFILE= RDKit 3D 24 25 0 0 0 0 0 0 0 0999 V2000 -2.0266 -2.3586 0.0180 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.2457 -1.1337 0.0194 N 0 0 0 0 0 0 0 0 0 0 0 0 0.0980 -1.2016 -0.0396 C 0 0 0 0 0 0 0 0 0 0 0 0 0.6640 -2.3330 -0.0957 O 0 0 0 0 0 0 0 0 0 0 0 0 0.8528 -0.0496 -0.0392 C 0 0 0 0 0 0 0 0 0 0 0 0 0.1667 1.1475 0.0238 C 0 0 0 0 0 0 0 0 0 0 0 0 1.1188 2.0980 0.0102 N 0 0 0 0 0 0 0 0 0 0 0 0 2.3424 1.5098 -0.0585 C 0 0 0 0 0 0 0 0 0 0 0 0 2.1777 0.1787 -0.0890 N 0 0 0 0 0 0 0 0 0 0 0 0 3.2218 -0.8442 -0.1623 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.1747 1.2258 0.0830 N 0 0 0 0 0 0 0 0 0 0 0 0 -1.8960 2.4788 0.1491 C 0 0 0 0 0 0 0 0 0 0 0 0 -1.8484 0.0624 0.0788 C 0 0 0 0 0 0 0 0 0 0 0 0 -3.0951 0.0905 0.1326 O 0 0 0 0 0 0 0 0 0 0 0 0 -1.3793 -3.2317 -0.1146 H 0 0 0 0 0 0 0 0 0 0 0 0 -2.5846 -2.4721 0.9517 H 0 0 0 0 0 0 0 0 0 0 0 0 -2.7439 -2.2969 -0.8303 H 0 0 0 0 0 0 0 0 0 0 0 0 3.3067 2.0061 -0.0855 H 0 0 0 0 0 0 0 0 0 0 0 0 4.2034 -0.3514 -0.1134 H 0 0 0 0 0 0 0 0 0 0 0 0 3.0350 -1.4069 -1.0867 H 0 0 0 0 0 0 0 0 0 0 0 0 3.0554 -1.5605 0.6904 H 0 0 0 0 0 0 0 0 0 0 0 0 -2.7349 2.4099 0.8974 H 0 0 0 0 0 0 0 0 0 0 0 0 -2.2597 2.7298 -0.8527 H 0 0 0 0 0 0 0 0 0 0 0 0 -1.2536 3.3030 0.5131 H 0 0 0 0 0 0 0 0 0 0 0 0 1 2 1 0 2 3 1 0 3 4 2 0 3 5 1 0 5 6 2 0 6 7 1 0 7 8 2 0 8 9 1 0 9 10 1 0 6 11 1 0 11 12 1 0 11 13 1 0 13 14 2 0 13 2 1 0 9 5 1 0 1 15 1 0 1 16 1 0 1 17 1 0 8 18 1 0 10 19 1 0 10 20 1 0 10 21 1 0 12 22 1 0 12 23 1 0 12 24 1 0 M END ##END= ##TITLE=Experimental spectrum ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR SPECTRUM ##BLOCK_ID=2 ##TEMPERATURE=NA ##.OBSERVE FREQUENCY=500 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=CDCl3 ##.SHIFT REFERENCE=INTERNAL,CHCl3 (Residual-Peak),None,None ##XUNITS=PPM ##FIRSTX=10.649622036279206 ##LASTX=-1.3503288362132384 ##MINX=-1.3503288362132384 ##MAXX=10.649622036279206 ##XFACTOR=0.00018310751312178297 ##NPOINTS=65536 ##YUNITS=ARBITRARY UNITS ##FIRSTY=1.2012541865793314 ##LASTY=0.42792983463604184 ##MINY=-3.9943154735954787 ##MAXY=10000.0 ##YFACTOR=0.3051850947599719 ##XYDATA=(X++(Y..Y)), XYDATA $$ DIF 58160D%m%%jKKkl%jJLj%Jj%J%%KjjjjJ%j%JjLjmKMJjl%Jk%MJmjJj%%J%%J%%jkJJJJjk%%jJKJlK 58086AJkk%KKk%KlkLJjJJj%jjjj%K%%Ljj%JJ%jjjj%K%J%k%J%%%J%kjJKj%JkjKKkkJLkkMJm%Ljj 58012@J%%%jJjk%%JJJ%Jjj%jJKjm%KJ%kKKkkK%JJlJLlj%JKklKKJ%kjJKKlkLmkL%J%kKJlL%lKjk 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-6955@JJkjJk%Njm%LJjjJJm%LjjKj%KljNklKjjKj%Kj%%%JjjK%J%mJ%jKJJJmkKJJJn%N%ljKJk%J -7029@j%KKlkLJmJ%kJ%%KkJKj%%jK%kJk%MljNjnJKjjJMkkLJl%j%K%k%%%J%%Kk%Kjk%jJKj%%Jjl -7103cJNjkJl%K%%j%KJkjJJjJ%lJLljMkj%%KJk%%%Kkj%jLLl%KkljK%jKJjKkkKjjN%m%JjjJLjk% -7177a%%%KKljMjnJLJkkKK%kkKKljLjjJjK%l%JJLj%jkJKljJ%JJk%JJ%kjJK%%j%jKJlkLJ%%k%JJ -7251AJjl%KJlJJkKMmjLljKkK%kKJjL%k%k%Jj%j%LkJMnkNlkNjk%jKK%kk%M%ljJKjkL%jKjlJJ%j -7325aK%kJLkk%jJMlkK%kKJjjJJ%k%Kj%%jJJjjJ%%J%jkKLljKkjJK -7375A $$ checkpoint ##END= ##TITLE=Simulated peaks ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK TABLE ##DATA CLASS=PEAK TABLE ##BLOCK_ID=3 ##TEMPERATURE=NA ##.OBSERVE FREQUENCY=500 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=CDCl3 ##NPOINTS=12 ##XUNITS=PPM ##YUNITS=ARBITRARY UNITS ##PEAK TABLE=(XY..XY) (3.410003662109375, 2000.2282252464001) (3.410003662109375, 2000.2282252464001) (3.410003662109375, 2000.2282252464001) (7.0500335693359375, 1999.3752832412697) (3.9939422607421875, 1994.5381721771791) (3.9939422607421875, 1994.5381721771791) (3.9939422607421875, 1994.5381721771791) (3.5869903564453125, 1999.9999999999998) (3.5869903564453125, 1999.9999999999998) (3.5869903564453125, 1999.9999999999998) (3.5869903564453125, 1999.9999999999998) (3.5869903564453125, 1999.9999999999998) ##END= ##TITLE=Assignments ##JCAMP-DX=5.01 ##ORIGIN=NP-MRD ##OWNER=NP-MRD ##DATA TYPE=NMR PEAK ASSIGNMENTS ##DATA CLASS=PEAK ASSIGNMENTS ##BLOCK_ID=4 ##CROSS REFERENCE=STRUCTURE:BLOCK_ID=1 ##TEMPERATURE=NA ##SOURCE REFERENCE=PMID 19212411 ##.OBSERVE FREQUENCY=500 ##.OBSERVE NUCLEUS=1H ##.SOLVENT NAME=CDCl3 ##NPOINTS=12 ##XUNITS=PPM ##PEAK ASSIGNMENTS=(XMA) (3.41, , <15>) (3.41, , <16>) (3.41, , <17>) (7.05, , <18>) (3.994, , <19>) (3.994, , <20>) (3.994, , <21>) (3.587, , <22>) (3.587, , <23>) (3.587, , <24>) (3.587, , <25>) (3.587, , <26>) ##END= ##END=